Natural_abundance

In chemistry, natural abundance (NA) refers to the prevalence of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average) of these isotopes is the atomic weight listed for the element in the periodic table. The abundance of an isotope varies from planet to planet but remains relatively constant in time.

As an example, uranium has three naturally occurring isotopes: U-238, U-235 and U-234. Their respective NA is 99.2745%, 0.72% and 0.0055%. For example, if 100,000 uranium atoms were analyzed, one would expect to find approximately 99,275 U-238 atoms, 720 U-235 atoms, and no more than 5 or 6 U-234 atoms. This is because U-238 is much more stable than U-235 or U-234, as the half-life of each isotope reveals: 4.468×10⁹ years for U-238 compared to 7.038×10⁸ years for U-235 and 245,500 years for U-234.

Deviations from natural abundance

We now know from study of the sun and primitive meteorites that our solar system was initially almost homogeneous in isotopic composition. Deviations from the (evolving) galactic average, locally-sampled around the time that the sun\'s nuclear burning began, can generally be accounted for by mass fractionation plus a limited number of nuclear decay and transmutation processesRobert N. Clayton (1978) Isotopic anomalies in the early solar system, Annual Review of Nuclear and Particle Science 28:501-522.. There is also evidence for injection of short-lived (now extinct) isotopes from a nearby supernova explosion that may have triggered solar nebula collapseErnst Zinner (2003) An isotopic view of the early solar system, Science 300:5617, 265-267.. Hence deviations from natural abundance on earth are often measured in parts per thousand (per mil or ‰) because they are less than one percent (%).

The single exception to this lies with the presolar grains found in primitive meteorites. These bypassed the homogenization, and often carry the nuclear signature of specific nucleosynthesis processes in which their elements were madeErnst Zinner (1998) Stellar nucleosynthesis and the isotopic composition of presolar grains from primitive meteorites, Annual Review of Earth and Planetary Sciences 26:147-188.. In these materials, deviations from "natural abundance" are sometimes measured in factors of 100.

See also

• Abundance of the chemical elements

Footnotes and References

External links

• Stable element isotopic abundance list from the NanoSIMS group at Washington University
• Berkeley Isotopes Project Interactive Table
• Scientific Instrument Services List

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